20240
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20240
Fluka
Bromo-tert-butyl(methoxy)phenylsilane
purum, ≥95.0% (GC)
| Synonym: | tert-Butyl(methoxy)phenylbromosilane, TBMPSiBr |
| CAS Number: | 94124-39-7 |
| Linear Formula: | C11H17BrOSi |
| Molecular Weight: | 273.24 |
| Beilstein Registry Number: | 4983916 |
| MDL number: | MFCD00043308 |
| PubChem Substance ID: | 24852061 |
Description
| Other Notes | Protecting group reagent for alcohols; derivatives are selectively cleaved with fluoride in the presence of other silyl ethers1,2 |
Properties
| grade | purum |
| assay | ≥95.0% (GC) |
| refractive index | n |
| bp | 80-82 °C/0.1 mmHg |
| density | 1.218 g/mL at 20 °C(lit.) |
Safety
| Personal Protective Equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN3265 8/PG 2 |
| WGK Germany | 3 |
| Flash Point(F) | 222.8 °F |
| Flash Point(C) | 106 °C |
References
| Cited Reference | 1. Y. Guindon et al. Tetrahedron Lett. 25, 4717, (1984) |
| 2. A.I. Mallet et al. J. Chromatogr. 378, 194, (1986) Abstract |
